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Cleanfast Super Bowl Blue Heavy Duty Toilet Cleaner MSDS

Cleanfast Super Bowl Blue Heavy Duty Toilet Cleaner MSDS

Cleanfast Super Bowl Blue Heavy Duty Toilet Cleaner MSDS

 

PRODUCT INFORMATION SHEET
SUPER BOWL BLUE
HEAVY DUTY TOILET DE-SCALER
PRODUCT INFORMATION:
A powerful cleaner, sanitizer & de-scaler suitable for use on all ceramic toilets & urinals. Regular use
will dissolve lime & uric scale as well as removing mould & mildew from grout & tiles. Avoid contact
with metal surfaces such as chrome, brass & stainless steel etc.
_________________________________________________________
ADVANTAGES:
CLEARS AWAY SCALE: Super Bowl immediately dissolves existing scale, even the most stubborn
deposits leaving sparking surfaces
KILLS GERMS & Along with physically cleaning surfaces of scale, mould, mildew & other
ALGAE: deposits it also has powerful germicidal action leaving surfaces hygienically
clean.
DEODORISES: Super Bowl quickly destroys bacteria & germs, clearing offensive odours.
SUITABLE IN HARD Even in the most hard water areas Super Bowl is exceptionally efficient at
OR SOFT WATER: scale removal.
LEAVES NO STREAKS: Super Bowl easily rinses off to leave a clean residue free surface
BIODEGRADABLE &: Fully biodegradable & 100% soluble in water.
WATER SOLUBLE:
___________________________________________________________
DIRECTIONS FOR USE:
For toilets: Direct bottle under the rim & apply evenly around the bowl. Allow time to penetrate, agitate
with toilet brush & flush. For Tiles & Grout brush or sponge directly onto surface, allow time to
penetrate & rinse off with water. Do not mix with other detergents especially bleach. Do not use on
chrome, brass or stainless steel etc.
____________________________________________________________
HEALTH AND SAFETY: See Safety Data Sheet.
____________________________________________________________
PACKAGING:
All our plastic drums are high molecular weight; high-density polyethylene designed to bring the
product to the customer in perfect conditions.
Size: 1Lt Duck Neck Bottle
___________________________________________________________
QUALITY ASSURANCE:
This product is manufactured in Ireland to ISO 9002 quality standards & conforms to R.E.A.C.H & CLP
regulations. Shelf life: Not less than 3 years.
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 1 of 7
Date of issue: 01.01.17 Replaces version of: 01.01.14
PRODUCT NAME: SUPER BOWL BLUE 12%
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1. Product identifier
Product Name SUPER BOWL BLUE 12%
Product No. BR 401
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Cleaning agent
1.3. Details of the supplier of the safety data sheet
Supplier Cleanfast.ie
Ashleigh House, JFK Road, Dublin 12
Tel: 1800 848700 (free) Email: info@fastdeal.ie
1.4. Emergency Contact: National Poisons Information Centre, Beaumont Hospital,
Beaumont Road, Dublin 9. Tel: +353(01)8092566
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification: Regulation (EC) No 1272/2008 H314, H335
Human health: Causes severe skin burns & eye damage. May cause respiratory irritation
Environment: This product is biodegradable & not expected to be hazardous to the
environment.
2.2. Label elements
Detergent Labelling: Contains: Hydrochloric Acid, Non-ionic surfactants
DANGER WARNING
Hazard Phrases H314 Causes severe skin burns & eye damage
H335 May cause respiratory irritation
Precautionary P102 Keep out of the reach of children
Statements P261 Avoid breathing vapours or spray mists
P262 Do not get in eyes, on skin or on clothing
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves, clothing, eye & face protection
P302 IF ON SKIN: Remove contaminated clothing & rinse skin
thoroughly with soap & water. Obtain medical attention if irritation
persists
P304 IF INHALED: Remove immediately from source to fresh air. Obtain
medical attention if any discomfort continues.
P305 IF IN EYES: Flush eyes with water, remove contact lenses if
present & continue rinsing. Obtain medical attention if irritation
persists.
P312 Call a poison centre or doctor/physician if you feel unwell
P403 Store in a well-ventilated place. Keep container tightly closed.
2.3. Other hazards N/A
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 2 of 7
Date of issue: 01.01.17 Replaces version of: 01.01.14
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
HYDROCHLORIC ACID …% 10-15%
CAS-No.: 7647-01-0 EC No.: 231-595-7
Classification (EC 1272/2008)
Skin Corr. 1B – H314
STOT SE 3 – H335
BETAINES, BIS-(1,2-ETHANEDIOL) TALLOW DIMETHYL 0-3%
CAS-No.: 70750-46-8 EC No.: 274-875-0
Classification (EC 1272/2008)
Skin Irrit. 2 – H315
Eye Dam. 2 – H319
A Full Text for all Hazard Statements are Displayed in Section 16
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation: Remove immediately from source to fresh air. Obtain medical attention if
any discomfort continues.
Skin Contact: Remove contaminated clothing & rinse skin thoroughly with soap & water.
Obtain medical attention if irritation persists.
Eye Contact: Flush eyes with water immediately. Obtain medical attention if irritation
persists.
Ingestion: Rinse out mouth immediately with water. Consult a doctor if irritation
persists.
Protection of
first aider: Avoid inhalation, contact with skin and eyes (see Section 8.)
4.2. Most important symptoms and effects, both acute and delayed
Inhalation: Spray mists may cause coughing, chest tightness, feeling of chest
pressure.
Ingestion: May cause discomfort if swallowed. May cause internal injury
Skin contact: May cause serious chemical burns to the skin.
Eye contact: Damaging to eyes & mucous membranes, including burning &
tearing.
4.3. Indication of any immediate medical attention and special treatment needed
The severity of the symptoms described will vary dependant of the concentration and the
length of exposure, first aid may still be required in case of accidental exposure, inhalation or
ingestion of this chemical. If in doubt, get medical attention promptly!
SECTION 5: FIRE FIGHTING MEASURES
5.1 Suitable Extinguishing Media: Extinguish with alcohol-resistant foam, carbon
dioxide, dry powder or water fog.
5.2 Unsuitable: N/A
5.3 Specific Hazards: Vaporises on heating to liberate highly irritating mists
of hydrochloric acid. May decompose in a fire to
generate irritating fumes. Attacks most metals,
liberating flammable hydrogen gas, which may form
an explosive mixture with air.
5.4 Special Equipment for the
protection of Fire Fighters: May generate toxic & explosive fumes in a fire,
therefore fire fighters should wear self-contained
breathing apparatus and full body protective clothing.
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 3 of 7
Date of issue: 01.01.17 Replaces version of: 01.01.14
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions: Avoid inhalation of spray mist & contact with skin and eyes.
Provide adequate ventilation (see Section 8.)
6.2 Environmental Precautions: If size of spillage warrants & has contaminated water
courses, drains or vegetation advise appropriate authorities.
6.3 Methods for Cleaning up: Small Spills – Flush with water.
Large Spills – Contain & collect spillage & absorb on to sand
SECTION 7: HANDLING AND STORAGE
7.1 Handling
Technical Measures: Eye wash facilities & emergency shower must be available
when handling this product..
Safe Handling Advice: Avoid inhalation of spray mist & contact with eyes and skin.
Comply with instructions for use.
7.2 Storage
Technical Measures: No special measures required.
Storage Conditions: Store in a cool dry place.
Incompatible Products: Alkalis, Strong Oxidizing Agents. Mild steel, cast iron,
aluminium, aluminium alloys, brasses, tinned and
galvanized materials are all attacked
Packaging: Plastic Drums.
Packaging Materials: Recommended: Plastic Materials, Polyethylene,
Polypropylene. Not Suitable – Uncoated Metal Drums.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Engineering Measures: No special measures required.
8.2 Personal Protection Equipment:
Respiratory Protection: If engineering controls do not maintain airborne
concentrations below recommended exposure limits, where
applicable an air-purifying respirator type ABEK (EN
14387) respirator cartridges must be worn.
Hand Protection: Use Chemical Resistant Gloves to EN Standard 374 Level
1, Letter Code K
Eye Protection: Use Chemical Goggles or Face Shield to EN Standard 166
Level 3 or higher
Skin Protection: Wear Plastic Apron EN Standard 13034 Type PB[6] & Face
Shield EN Standard 166 Level 3 or higher
8.3 Hygiene Measures: Handle in accordance with good industrial hygiene & safety
practices.
8.4 Occupational Exposure Limits:
Safety Data Sheet
Name STD Occupational Exposure
Limit Value (8-hour
reference period)
ppm mg/m3
Occupational Exposure
Limit Value (15 minute
reference period)
ppm mg/m3
Notes
HYDROCHLORIC
ACID
OELV 5 8 10 15 IOELV
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 4 of 7
Date of issue: 01.01.17 Replaces version of: 01.01.14
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
a) Appearance: Viscous Blue Liquid.
b) Odour: Fresh Fragrant
c) Odour threshold: N/A
d) pH: 1+/-0.5 (undiluted)
e) Melting point / freezing point: No data available
f) Initial boiling point & boiling range: No data available
g) Flash point: No data available
h) Evaporation rate: No data available
i) Flammability solid, gas): No data available
j) Upper/lower flammability or explosive limits: No data available
k) Vapour pressure: No data available
l) Vapour density: No data available
m) Relative density: 1.05kg/dm3
n) Solubility(ies): Soluble in Water
o) Partition coefficient: n-octanol/water: No data available
p) Auto-ignition temperature: No data available
q) Decomposition temperature: No data available
r) Viscosity: No data available
s) Explosive properties: No data available
t) Oxidising properties: No data available
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: There are no known reactivity hazards
associated with this product.
10.2. Chemical stability: Stable under normal temperature conditions
and recommended use.
10.3. Possibility of hazardous reactions: Contact with concentrated Sulphuric acid will
liberate irritating fumes of Hydrogen
Chloride Gas. Contact with conc. Nitric Acid
liberates toxic fumes of Nitrosyl Chloride.
Can liberate harmful gases from certain
chemicals & Salts e.g. Cyanides, Nitrites,
sulphites, Acetylides and Carbides. Reacts
with oxidising agents to liberate toxic Chlorine
Gas. Reactions with concentrated Alkalis
generate much heat. Liberates Carbon
Dioxide from carbonates and bicarbonates
Corrosive to most metals
10.4. Conditions to avoid: Avoid Extreme Temperatures. Avoid contact
with alkalis &/or oxidising agents.
10.5. Incompatible materials: Alkalis &/or oxidizing agents, most metals.
10.6. Hazardous decomposition products: Hydrogen chloride (HCl).
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 5 of 7
Date of issue: 01.01.17 Replaces version of: 01.01.14
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects:
Inhalation: Irritating to respiratory system. Prolonged inhalation of high concentrations may
damage respiratory system.
Ingestion: Causes burns. Swallowing concentrated chemical may cause severe internal
injury. May cause chemical burns in mouth, oesophagus and stomach.
Skin contact: Corrosive and Irritating to skin. Will burn skin on contact
Eye contact: Risk of serious damage to eyes. Causes burns. Contact with concentrated
chemical may very rapidly cause severe eye damage, possibly loss of sight.
HYDROCHLORIC ACID 36% (CAS-No.: 7647-01-0)
Acute toxicity:
Acute Toxicity (Oral LD50)
No LD50 available. Will immediately cause corrosion of & damage to the
gastrointestinal tract
Acute Toxicity (Dermal LD50)
No LD50 available. Will immediately cause corrosion of & damage to the skin
Acute Toxicity (Inhalation LC50)
No LC50 4 hour available
LC50 Rat (5 min exposure to aerosol of aqueous solution) 45.6mg/l
LC50 Rat (30 min exposure to aerosol of aqueous solution) 8.3mg/l
REACH dossier information
SECTION 12: ECOLOGICAL INFORMATION
Eco-toxicity
The product components are not classified as environmentally hazardous. However, this
product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic
organisms. Large or frequent spills can have a harmful or damaging effect on the environment
12.1. Toxicity
Ecological information on ingredients:
HYDROCHLORIC ACID (CAS: 7647-01-0)
Acute Toxicity – Fish
LC50 96 hours 20.5 mg/l
REACH dossier information
Acute Toxicity – Aquatic Invertebrates
EC50 48 hours 0.45 mg/l Daphnia magna
REACH dossier information
Acute Toxicity – Aquatic Plants
EC50 72 hours 0.73 mg/l
REACH dossier information
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 6 of 7
Date of issue: 01.01.17 Replaces version of: 01.01.14
12.2. Persistence and degradability
Degradability: The surfactant(s) contained in this preparation comply with the
biodegradability criteria as laid down in Regulation (EC) No.648/2004 on
detergents. Data to support this assertion are held at the disposal of the
competent authorities of the Member States and will be made available to
them, at their direct request or at the request of a detergent manufacturer.
Ecological information on ingredients.
HYDROCHLORIC ACID (CAS: 7647-01-0)
Degradability. This product is expected to be easily biodegradable.
12.3. Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating.
Ecological information on ingredients
HYDROCHLORIC ACID (CAS: 7647-01-0)
Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating
12.4. Mobility in soil
Mobility: The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not determined.
12.6. Other adverse effects
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
General information: Waste to be treated as controlled waste. Disposal to licensed
waste disposal site in accordance with local Waste Disposal
Authority
13.1. Waste treatment methods
Dispose of waste in accordance with local regulations. Recover, reclaim or recycle, where
possible.
SECTION 14: TRANSPORT INFORMATION
The product is not covered by international regulation on the transport of dangerous goods:
REGULATIONS CLASS
RID/ADR: Not Classified
ICAO/IATA-DGR: Not Classified
GGVSee/IMDG-Code: Not Classified
14.1. UN number N/A
14.2. UN proper shipping name N/A
14.3. Transport hazard class(es) N/A
14.4. Packing Group N/A
14.5. Environmental Hazards
Environmentally Hazardous Substance/Marine Pollutant: N/A
14.6. Special precautions for user N/A
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 7 of 7
Date of issue: 01.01.17 Replaces version of: 01.01.14
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
Statutory Instruments
Corresponding to Preparations Regulations S.I. No. 62 of 2004
Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply.
6 / 7
Guidance Notes
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures,
amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation
(EC) No 1907/2006 with amendments.
15.2. Chemical Safety Assessment
No chemical safety assessment has been carried out.
SECTION 16: OTHER INFORMATION
Revision Comments
Re-issued according to Regulation (EU) No 453/2010.
Revision Date: 01.01.17
Revision No: 4
Replaces version of: 01.01.14
Hazard Statements In Full
H314 Causes severe skin burns & eye damage
H335 May cause respiratory irritation
H315 Causes skin irritation
H319 Causes serious eye irritation
__________________________________________________________________________
The information contained herein is based on the present state of our knowledge and is
intended to describe our products from the point of view of safety requirements. It should
therefore not be construed as guaranteeing specific properties.

 

Cleanfast Super Bowl Blue Heavy Duty Toilet Cleaner MSDS

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