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Cleanfast Duck Fresh Toilet Cleaner & Descaler Data Sheet MSDS

PRODUCT INFORMATION SHEET
DUCK FRESH
DAILY TOILET CLEANER
PRODUCT INFORMATION:
An all-purpose cleaner & deodorizer suitable for toilets, urinals, sinks & all hard surfaces. Clings to the
surface leaving a clean & fresh surface. Regular use helps prevent lime scale build-up.
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ADVANTAGES:
POWERFUL CLEANING Duck Fresh clings to the surface & as it contains a blend of anionic
ACTION: surfactants, wetting & emulsifying agents it quickly penetrates emulsifies
& removes soiling quickly & efficiently.
SCALE PREVENTION: Regular use helps prevent lime & uric scale build up in toilets & urinals.
FRESH FRAGRANCE: Duck Fresh leaves a summer fresh & clean fragrance after use.
NON-STREAKING: Rinses from the toilet surface to leave a clean, sparking, streak &
residue free surface.
FAST ACTING AND Effective within moments of application & can be applied
VERSATILE: easily to all surfaces.
BIODEGRADABLE: Readily biodegradable water based cleaner.
SOLUBILITY: 100% soluble in water.
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DIRECTIONS FOR USE:
Direct bottle under the rim & apply evenly around the bowl (or other surfaces). For best results leave
on the surface for a few minutes then agitate with a toilet brush before flushing.
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HEALTH AND SAFETY: See Safety Data Sheet.
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PACKAGING:
All our plastic drums are high molecular weight; high-density polyethylene designed to bring the
product to the customer in perfect conditions.
Size: 1Lt Duck Neck Bottle
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QUALITY ASSURANCE:
This product is manufactured in Ireland to ISO 9002 quality standards & conforms to R.E.A.C.H & CLP
regulations. Shelf life: Not less than 3 years.
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 1 of 7
Date of issue: 01.01.17 Replaces version of: 01.01.15
PRODUCT NAME: DUCK FRESH
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1. Product identifier
Product Name DUCK FRESH
Product No. BR 404
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Cleaning agent
1.3. Details of the supplier of the safety data sheet
Supplier Cleanfast.ie
Ashleigh House, JFK Road, Dublin 12
Tel: 1800 848700 (free) Email: info@fastdeal.ie
1.4. Emergency Contact: National Poisons Information Centre, Beaumont Hospital,
Beaumont Road, Dublin 9. Tel: +353(01)8092566
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification: Regulation (EC) No 1272/2008: H319
Human health: Causes serious eye irritation
Environment: This product is Readily Biodegradable and not expected to be hazardous
to the environment.
2.2. Label elements
Detergent Labelling: Contains: Propon-2-ol, phosphoric acid, non-ionic & anionic surfactants
WARNING
Hazard Phrases H319 Causes serious eye irritation
Precautionary P102 Keep out of the reach of children
Statements P264 Wash hands thoroughly after handling
P280 Wear eye protection.
P305 IF IN EYES: Flush eyes with water, remove contact lenses if
present & continue rinsing. Obtain medical attention if irritation
persists.
2.3. Other hazards N/A
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 2 of 8
Date of issue: 01.01.17 Replaces version of: 01.01.16
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
SODIUM LAURYL ETHER SULPHATE 5-10%
CAS-No.: 68585-34-2 EC No.: 221-416-0
Classification (EC 1272/2008)
Eye Irrit. 2 – H319
COCONUT DIETHANOLAMIDE 1-5%
CAS-No.: 8051-30-7 EC No.:
Classification (EC 1272/2008)
Skin Irrit. 2 – H315
Eye Dam. 1 – H318
1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-coco acyl derivs.,
hydroxides, inner salts 0-1%
CAS-No.: 61789-40-0 EC No.: 263-058-8
Classification (EC 1272/2008)
Skin Irrit. 2 – H315
Eye Dam. 2 – H319
ALCOHOL ETHOXYLATE 0-1%
CAS-No.: 102782-43-4 EC No.: 809-915-7
Classification (EC 1272/2008)
Skin Irrit. 2 – H315
Eye Dam. 2 – H319
PROPAN-2-OL 0-1%
CAS-No.: 67-63-0 EC No.: 200-661-7
Classification (EC 1272/2008)
Flam. Liq. 2 – H225
Eye Irrit. 2 – H319
STOT SE 3 – H336
PHOSPHORIC ACID 0-1%
CAS-No.: 7664-38-2 EC No.: 231-633-2
Classification (EC 1272/2008)
Skin Corr. 1B – H314
A Full Text for all Hazard Statements are Displayed in Section 16
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation: Not relevant. Inhalation unlikely. In case of inhalation of spray mist: Move
person into fresh air and keep at rest.
Ingestion: DO NOT INDUCE VOMITING! Drink a few glasses of water or milk. Get
medical attention if any discomfort continues.
Skin contact: Wash skin with soap and water.
Eye contact: Flush eyes with water, remove contact lenses if present & continue
rinsing. Obtain medical attention if irritation persists.
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 3 of 8
Date of issue: 01.01.17 Replaces version of: 01.01.16
4.2. Most important symptoms and effects, both acute and delayed
Inhalation: No symptoms noted.
Ingestion: No specific symptoms noted but may cause discomfort if swallowed
Skin contact: No specific symptoms noted bur prolonged or excessive exposure may
cause skin dryness.
Eye contact: Will cause irritation eyes. May cause serious damage to eyes by affecting
the natural lubrication of the eye & cause redness &/or tearing.
4.3. Indication of any immediate medical attention and special treatment needed
The severity of the symptoms described will vary dependant of the concentration and the
length of exposure.
SECTION 5: FIRE FIGHTING MEASURES
5.1 Suitable Extinguishing Media: This product is flammable. Use appropriate
extinguishing media for surrounding materials
5.2 Unsuitable: N/A
5.3 Specific Hazards: Avoid breathing fire vapours. Harmful vapours or
gases may be formed in a fire
5.4 Special Equipment for the
protection of Fire Fighters: Wear full protective clothing & breathing apparatus.

SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions: None required (see Section 8.)
6.2 Environmental Precautions: No special measures required
6.3 Methods for Cleaning up: Small Spills – Flush with water.
Large Spills – Contain and collect
spillage and absorb on to sand for disposal.
SECTION 7: HANDLING AND STORAGE
7.1 Handling
Technical Measures: No special measures required.
Safe Handling Advice: None noted. Comply with instructions for use.
7.2 Storage
Technical Measures: No special measures required.
Storage Conditions: Store in a cool dry place away from oxidizing agents.
Incompatible Products: None known.
Packaging: Plastic Drums.
Packaging Materials: Recommended: Plastic Materials, Polyethylene,
Polypropylene.
Not Suitable – N/A.
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 4 of 8
Date of issue: 01.01.17 Replaces version of: 01.01.16
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Engineering Measures: No special measures required.
8.2 Personal Protection Equipment:
Respiratory Protection: Provide adequate ventilation in areas of confined space.
Hand Protection: None Required
Eye Protection: Use Chemical Goggles or Face Shield to EN Standard 166
Level 3 or higher
Skin Protection: None Required
8.3 Hygiene Measures: Handle in accordance with good industrial hygiene and
safety practices.
8.4 Occupational Exposure Limits:
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
a) Appearance: Viscous blue liquid.
b) Odour: Fragrant
c) Odour threshold: N/A
d) pH: 7+/-0.5
e) Melting point / freezing point: No data available
f) Initial boiling point & boiling range: 100°C
g) Flash point: No data available
h) Evaporation rate: No data available
i) Flammability solid, gas): No data available
j) Upper/lower flammability or explosive limits: No data available
k) Vapour pressure: No data available
l) Vapour density: No data available
m) Relative density: 1.01kg/dm3
n) Solubility(ies): Soluble in Water
o) Partition coefficient: n-octanol/water: No data available
p) Auto-ignition temperature: No data available
q) Decomposition temperature: No data available
r) Viscosity: No data available
s) Explosive properties: No data available
t) Oxidising properties: No data available
Name STD Occupational Exposure
Limit Value (8-hour
reference period)
ppm mg/m3
Occupational Exposure
Limit Value (15 minute
reference period)
Ppm mg/m3
Notes
PROPAN-2-OL OELV 200 – 400 –
PHOSPHORIC ACID OELV – 1 mg/m3 – 2 mg/m3
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 5 of 8
Date of issue: 01.01.17 Replaces version of: 01.01.16
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: There are no known reactivity hazards
associated with this product.
10.2. Chemical stability: Stable under normal temperature conditions
and recommended use.
10.3. Possibility of hazardous reactions: Hazardous Polymerisation N/A
10.4. Conditions to avoid: Do not mix with strong acids or oxidising
agents.
10.5. Incompatible materials: Strong acids or oxidising agents.
10.6. Hazardous decomposition products: None under normal conditions.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects:
Inhalation: No symptoms noted.
Ingestion: No specific symptoms noted but may cause discomfort if swallowed
Skin contact: No specific symptoms noted bur prolonged or excessive exposure may
cause skin dryness.
Eye contact: Will cause irritation eyes. May cause serious damage to eyes by affecting
the natural lubrication of the eye & cause redness &/or tearing
11.2.Toxicological information on ingredients:
SODIUM LAURYL ETHER SULPHATE (CAS: 68585-34-2)
Acute Toxicity (Oral LD50)
1600 mg/kg Rat
Miscellaneous information sources
COCONUT DIETHANOLAMIDE (CAS: 8051-30-7)
Acute Toxicity (Oral LD50)
> 2000 mg/kg Rat
IUCLID chemical data sheet
PROPAN-2-OL (CAS: 67-63-0)
Acute Toxicity (Oral LD50)
5.84 g/kg Rat
Acute Toxicity (Dermal LD50)
16.4 mL/kg Rabbit
Acute Toxicity (Inhalation LC50)
> 10000 ppm (vapours) Rat
REACH dossier information
PHOSPHORIC ACID (CAS: 7664-38-2)
Toxic Dose 1 – LD 50
>1530
Acute Toxicity (Dermal LD50)
>2740 mg/kg Rabbit
REACH dossier information
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 6 of 8
Date of issue: 01.01.17 Replaces version of: 01.01.16
SECTION 12: ECOLOGICAL INFORMATION
Eco-toxicity
Not regarded as dangerous for the environment. The product is easily biodegradable.
12.1. Toxicity
Ecological information on ingredients:
SODIUM LAURYL ETHER SULPHATE (CAS: 68585-34-2)
No Information Available
COCONUT DIETHANOLAMIDE (CAS: 8051-30-7)
Acute Toxicity – Fish
LC50 96 hours 5.4 mg/l Brachydanio rerio (Zebra Fish)
Acute Toxicity – Aquatic Invertebrates
EC50 48 hours 2.39 mg/l Daphnia magna
Acute Toxicity – Aquatic Plants
EC50 96 hours 2.3 mg/l Scenedesmus acutus
IUCLID chemical data sheet.
PROPAN-2-OL (CAS: 67-63-0)
Acute Toxicity – Fish
LC50 9640 mg/l Pimephales promelas (Fat-head Minnow)
Acute Toxicity – Aquatic Invertebrates
LC50 24 hours > 10000 mg/l Daphnia magna
Acute Toxicity – Aquatic Plants
Toxicity threshold 168 hours 1800 mg/l Scenedesmus quadricauda
REACH dossier information
PHOSPHORIC ACID (CAS: 7664-38-2)
Acute Toxicity – Fish
LC50 96 hours 702 μg/L Pimephales promelas (Fat-head Minnow)
REACH dossier information
Acute Toxicity – Aquatic Invertebrates
EC50 48 hours 0.67 mg/l Daphnia magna
REACH dossier information
Acute Toxicity – Aquatic Plants
EC50 72 hours 8 mg/l Desmodesmus subspicatus
REACH dossier information
12.2. Persistence and degradability
Degradability: The surfactant(s) contained in this preparation comply with the
biodegradability criteria as laid down in Regulation (EC) No.648/2004 on
detergents. Data to support this assertion are held at the disposal of the
competent authorities of the Member States and will be made available to
them, at their direct request or at the request of a detergent manufacturer.
Ecological information on ingredients.
PHOSPHORIC ACID (CAS: 7664-38-2)
Degradability
This product mainly consists of inorganic compounds which are not biodegradable. The
remaining compounds of the product are expected to
be easily biodegradable
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 7 of 8
Date of issue: 01.01.17 Replaces version of: 01.01.16
12.3. Bioaccumulative potential
No data available on bioaccumulation.
12.5. Results of PBT and vPvB assessment
Not determined.
12.6. Other adverse effects
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
General information: Small amounts (less than 5 Litres) of unwanted product may be
flushed with water to sewer. Larger volumes must be sent for
disposal to licensed waste disposal site in accordance with local
Waste Disposal Authority. Consign empty container to normal
waste.
13.1. Waste treatment methods
Dispose of waste in accordance with local regulations. Recover, reclaim or recycle, where
possible.
SECTION 14: TRANSPORT INFORMATION
The product is not covered by international regulation on the transport of dangerous goods:
REGULATIONS CLASS
RID/ADR: N/A
ICAO/IATA-DGR: N/A
GGVSee/IMDG-Code: N/A
14.1. UN number None
14.2. UN proper shipping name None
14.3. Transport hazard class(es) N/A.
14.4. Packing Group N/A
14.5. Environmental Hazards None known
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
Statutory Instruments
Corresponding to Preparations Regulations S.I. No. 62 of 2004
Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply.
Guidance Notes
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures,
amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation
(EC) No 1907/2006 with amendments.
15.2. Chemical Safety Assessment
No chemical safety assessment has been carried out.
Safety Data Sheet
Corresponding to Regulation (EC) No 1272/2008 (CLP) Page 8 of 8
Date of issue: 01.01.17 Replaces version of: 01.01.16
SECTION 16: OTHER INFORMATION
Revision Comments
Re-issued according to Regulation (EU) No 453/2010.
Revision Date: 01.01.17
Revision No: 5
Replaces version of: 01.01.16
Hazard Statements In Full
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H318 Causes serious eye damage
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness
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The information contained herein is based on the present state of our knowledge and is
intended to describe our products from the point of view of safety requirements. It should
therefore not be construed as guaranteeing specific properties.

Cleanfast Duck Fresh Toilet Cleaner & Descaler Data Sheet MSDS